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Our 5 work packages

Our project is building on 7 core principles:

  1. Solubility

  2. Phase diagrams

  3. Viscosity

  4. Mass transfer models

  5. Extrusion design

  6. Polymerization and/or reaction kinetics

  7. Process design elements

 

These have been developed into 5 work packages with 3 platform technologies. 

  1. Extrusion

  2. Extraction/Insertion

  3. Chemical modification

These 3 platform technologies make up the first three work packages. The fourth is about synergy between these technologies and the fifth is about communication and sharing knowledge with companies to set up green chemical processes. And in light of that fifth package, we cordially welcome you to our Industry 2030 Expo.

5. Knowledge center

By sharing and disseminating the knowledge gained with companies, we can help them set up more sustainable and ecofriendly processes.

2. Extraction/Insertion

Using scCO2 as a solvent, it is possible to either extract something from a material or to insert something in it. Based on mass transfer models, we can design process elements.

This will help with both separating and mixing of substances. Clean scCO2 will wash a material by extracting components. Substances that are dissolved in scCO2 will be inserted into a material.

4. Reinforcing platform technologies

By exchanging knowledge obtained in other work packages, each platform technology might be improved as the 7 core principles still apply across work packages.

Better insights will lead to better designs.

3. Chemical modification

Using scCO2 as a solvent, chemical reactions may benefit due to improved mass transfer. It is also possible to use CO2 as a reactant.

1. Extrusion

Using scCO2 as a plasticizer will allow for a decrease in mechanical energy requirements for extrusion processes due to lower viscosity of the melt. 

12 Principles of Green Chemistry

The chemical industry is aware that some practices are more sustainable than others, and to get a better grip on the concept, we've devised 12 principles of green chemistry practices:

  1. Prevention: It is better to prevent waste than to treat or clean up waste after it has been created.

  2. Atom Economy: Synthetic methods should be designed to maximize the incorporation of all materials used in the process into the final product.

  3. Less Hazardous Chemical Syntheses: Wherever practicable, synthetic methods should be designed to use and generate substances that possess little or no toxicity to human health and the environment.

  4. Designing Safer Chemicals: Chemical products should be designed to preserve the efficacy of function while reducing toxicity.

  5. Safer Solvents and Auxiliaries: The use of auxiliary substances (e.g., solvents, separation agents, etc.) should be made unnecessary wherever possible and, innocuous when used.

  6. Design for Energy Efficiency: Energy requirements should be recognized for their environmental and economic impacts and should be minimized. Synthetic methods should be conducted at ambient temperature and pressure.

  7. Use of Renewable Feedstocks: A raw material or feedstock should be renewable rather than depleting whenever technically and economically practicable.

  8. Reduce Derivatives: Unnecessary derivatization (use of blocking groups, protection/deprotection, temporary modification of physical/chemical processes) should be minimized or avoided if possible because such steps require additional reagents and can generate waste.

  9. Catalysis: Catalytic reagents [red. chemicals that aren't consumed in the reaction, multi-use] (as selective as possible) are superior to stoichiometric reagents [red. chemicals that are consumed during the reaction, single-use].

  10. Design for Degradation: Chemical products should be designed so that at the end of their function they break down into innocuous degradation products and do not persist in the environment.

  11. Real-time analysis for Pollution Prevention: Analytical methodologies need to be further developed to allow for real-time, in-process monitoring and control prior to the formation of hazardous substances.

  12. Inherently Safer Chemistry for Accident Prevention: Substances and the form of a substance used in a chemical process should be chosen to minimize the potential for chemical accidents, including releases, explosions, and fires.

12 is a bit of an unruly number though, even Moses came down the mountain with only 10, but fortunately, these 12 principles can be grouped together into 3 major categories:

  1. Safety: 3, 4, 5, 12

  2. Efficiency: 1, 2, 6, 8, 9

  3. Sustainability: 7, 8, 10, 11

Yes, some principles fall into more than one category, but there is quite some overlap in these principles. Working more efficiently with what you have goes a long way toward sustainability. Our pine tree symbolizes the unity of these categories of the 12 principles we should all strive for in our industrial practices.

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